You can only use PC2 if your chipset is enabled for it, I doubt it in your situation.
It must be enabled, I tried the option from the site you listed for recommendations based on machine, it showed PC2 also. Yet another FM computer solution.

(No insult to you, just commenting on these weird things that happen. FM is Army commo slang for Freakin' Magic used whenever something works and you don't know how. Actually the "F" is something I cannot post.

)
Basically, if your motherboard can support faster RAM, you should consider upgrading the RAM, but the CPU and Video Card should be priorities. A faster CPU and a faster Video Card with more video RAM should boost performance in Trainz more than faster RAM will.
I have done the video card. My Vista Performance Index Score in the video areas went up a lot from that, now looks like this
ProcessorIntel(R) Pentium(R) D CPU 3.00GHz
4.8
Memory (RAM)1.00 GB
4.5
GraphicsNVIDIA GeForce 8500 GT
4.9
Gaming graphics766 MB Total available graphics memory
5.3
Primary hard disk123GB Free (223GB Total)
5.4
Interesting, I just noticed from trying to print the Score, my graphics show 766MB of memory, 512 from the video board and 254 shared from RAM. Is that normal or should I turn the 254 off?
Here's the rest of what I was sent by the manufacturer (this is before I had the video card):
I would like to inform you that this is your system specification below.
Motherboard Intel . 2
CPU Intel Pentium D 925 3.0 GHz (Dual Core)
Memory 1024 MB (2x512MB) DDR2 PC4200 (533MHz) DIMM
Power Supply (Various) ATX 300 Watt
Video Intel GMA 950
Audio Intel SigmaTel 9220
Hard Drive (Various) SATA 8MB Cache 250 GB 7200 8MB
Primary Optical Drive [DVD-R/RW] 16x6x8x4x40x24x16x40x DVD+/-RW
Dual-Layer Burner (Various)
Sec. Optical Drive
Floppy Drive No Floppy Drive
* Special Drive #1 (Various) 15-in-1 Digital Media Reader
Modem Conexant 56K ITU v.92 Fax/Modem
Network Interface Intel PRO/100VE
USB Ports (FRONT/SIDE) 2
USB Ports (REAR) 4
Firewire Ports (FRONT/SIDE) 0
Firewire Ports (REAR) 0
And this is your motherboard specification.
Form Factor Micro ATX
CPU Socket/Slot Type LGA775
Chipset Intel 945G
RAM Type (Various) DDR2 PC5300 (667MHz) DIMM
Number of RAM Slots 2
Total RAM Capacity 4096
RAM Stick Size Limit 2048
BIOS/CMOS
Front Side Bus Speed 1066/800/533 MHz
ISA Slots 0
PCI Slots 2
PCI Express 1x Slots 1
PCI Express 16x Slots 1
EIDE Headers 0
Serial ATA Connectors 4
AGP Slots 0
AMR Slots 0
CNR Slots 0
Onboard Video Intel GMA 950 Integrated PCI-E
Onboard Audio Intel SigmaTel 9220
Battery CR2032
PS/2 Ports 2
Parallel Ports 1
Serial Ports 1
VGA Ports 1
DVI-I Ports 0
SVideo In Ports 0
SVideo Out Ports 0
RCA Ports 0
Microphone Ports (Front) 0
Microphone Ports (Back) 1
MIDI/Game Ports (Front) 0
MIDI/Game Ports (Back) 0
Audio/Line In Ports (Front) 0
Audio/Line In Ports (Back) 1
Spk./Headph. Ports (Front) 0
Spk./Headph. Ports (Back) 1
USB Ports by Header (Front) 0 (Version 2.0)
USB Ports (Back) 4 (Version 2.0)
Firewire Ports (Front) 0
Firewire Ports (Back) 0
RJ-11 (Phone) Ports (Front) 0
RJ-11 (Phone) Ports (Back) 0
RJ-45 (NIC) Ports (Front) 0 (Intel 82562G 10/100)
RJ-45 (NIC) Ports (Back) 1 (Intel 82562G 10/100)